4-Nitro-m-Phenylenediamine

AKA: 5131-58-8, 4-Nitro-1, 3-phenylenediamine, 2, 4-Diaminonitrobenzene, 4-NITRO-1, 3-BENZENEDIAMINE, 1, 3-Benzenediamine, 3-Diamino-4-nitrobenzene, 3-diaminobenzene, C.I. 76030
Allergen Warning
⚠️ PPD (Hair Dye)
Synthetic
Not Clean
4-nitro-m-phenylenediamine (CI 76030)
Solubility less than 1 mg/mL at 68.9 °F (NTP, 1992)
Formula
C6H7N3O2
Mol. Weight
153.14
CAS #
5131-58-8
Form
Liquid
State
4-nitro-1,3-benzenediamine appears as orange prisms with blue luster or yellow crystalline solid. (NTP, 1992)
Functions
Hair Dyeing
Colors Hair
Traditional Use
A synthetic hair dye ingredient developed in the early 20th century. One of the key components in permanent hair coloring chemistry, designed to replace earlier plant-based colorants like indigo and henna.
EWG
3
CIR
Insufficient data
Pregnancy
No
CIR Safety Findings
all-shades-safe
Potential Sensitizer
Regulatory Status
USAunder review
EUpermitted
JAPANpermitted
CANADApermitted
Skin Types
all-skin-types
Best For
General
Pregnancy & Breastfeeding Safe
No
The paper trail
🔬Peer-reviewednone on file
⚖️Regulatory0 listings
🛡️Safety-assessed1 review
Counts, not a verdict. A listing isn't a study. The trail, you decide.
Verified Jun 2026
Data: PubChem · CosIng · EWG · CIR